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Here is the Wild Zone 4 Spinarak wall for Attack EVs. (So used to saying route instead of Wild Zone lol)
For Attack, Route 4 is excellent with the wall of Spinaraks The Kakuna tree is mentioned here which is excellent for Defense
nvm. If anyone's reading this reply, I found the EV Yield page. Just look that up and you can find the remaining ones that aren't listed. I think it should be linked under each stat yield in case others are looking for more pokemon with that specific stat yield drop.
Does anyone know what other pokemon drop specific EVs besides the ones listed? I tried farming the snorunts and gogoats in wild area 12 for HP EVs, and the spawn timers are like 5 minutes or so. It's a little time consuming standing around every 5 minutes, or having to find something else to do, because I'd forget and kill other pokemon and mess up my EV training lol. Teleporting or bench resetting doesn't respawn them either.
I might suggest adding at least one overworld location to your rotation: the rooftop in Jaune Sector 4 with Alpha Pigeot has a 4 Pidgeys, 2 Pigeotto, and 1 Pigeot, for a total of 11 Speed EVs with every clear. As long as you're able to handle a Level 45 Pidgeot, it's probably the single fastest source of Speed EVs.