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Ascendant's Grip is a Yellow tool that lets you cling to walls in Hollow Knight: Silksong. Check out how to get Ascendant's Grip, its location, and its effects here!
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Ascendant's Grip can be purchased for 350 Rosaries from Jubilana at Songclave. Make sure to gather enough Rosaries before buying or crafting this tool.
To unlock Jubilana as a vendor, players will need to rescue her in the Choral Chambers during the wish The Wandering Merchant. This wish can be accepted at Songclave, before heading left to track her down immediately.
The Wandering Merchant Walkthrough

The Ascendant's Grip allows Hornet to stick to the wall when using her wall jump instead of sliding down. To grip onto walls, hold down the direction that will move Hornet into the wall.
This can be used in long platforming sections such as the Cogwork Core or Mount Fay, to give yourself a break and prepare for trickier sections. The Ascendant's Grip is also useful in fights where Hornet wants to stay in the air, such as the High Halls gauntlet.
This as well as the harp tool can be purchased from the merchant in songclave after completing both wishwall quests involving her.